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The Physical Basis of Thermodynamics - With Applications to Chemistry | Pascal Richet | Springer

About the book. Search in this book. Physical Chemistry: Concepts and Theory provides a comprehensive overview of physical and theoretical chemistry while focusing on the basic principles that unite the sub-disciplines of the field.


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With an emphasis on multidisciplinary, as well as interdisciplinary applications, the book extensively reviews fundamental principles and presents recent research to help the reader make logical connections between the theory and application of physical chemistry concepts. Purchase the book. We use cookies to help provide and enhance our service and tailor content and ads.

Thermodynamics: Crash Course Physics #23

It has its roots in the latter part of the 19th century, when atomic and molecular theories of matter began to be generally accepted. The application of thermodynamic principles begins by defining a system that is in some sense distinct from its surroundings. For example, the system could be a sample of gas inside a cylinder with a movable piston , an entire steam engine , a marathon runner, the planet Earth , a neutron star , a black hole , or even the entire universe.

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In general, systems are free to exchange heat , work , and other forms of energy with their surroundings. For a gas in a cylinder with a movable piston , the state of the system is identified by the temperature , pressure , and volume of the gas. These properties are characteristic parameters that have definite values at each state and are independent of the way in which the system arrived at that state. In other words, any change in value of a property depends only on the initial and final states of the system, not on the path followed by the system from one state to another.

Such properties are called state functions.

With Applications to Chemistry

In contrast, the work done as the piston moves and the gas expands and the heat the gas absorbs from its surroundings depend on the detailed way in which the expansion occurs. By isolating samples of material whose states and properties can be controlled and manipulated, properties and their interrelations can be studied as the system changes from state to state. You are using an outdated browser.

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